Dinitrogen binding at vanadium in a tris(alkoxide) ligand environment.
نویسندگان
چکیده
We report the first tris(alkoxide)V(III) complex to bind dinitrogen. Removal of THF from V(OR)(3)THF furnishes the highly reactive V(OR)(3) fragment, which binds dinitrogen to form [V(OR)(3)](2)(μ-N(2)) in the solid state. Dinitrogen is readily released upon dissolution of the complex. Structural and DFT studies are consistent with significant activation of N(2) when bound by the vanadium tris(alkoxide) platform.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 37 شماره
صفحات -
تاریخ انتشار 2011